Les fluoronitrures de terres rares
Identifieur interne : 004C86 ( Main/Exploration ); précédent : 004C85; suivant : 004C87Les fluoronitrures de terres rares
Auteurs : Michel Pezat [France] ; Bernard Tanguy [France] ; Marcus Vlasse [France] ; Josik Portier [France] ; Paul Hagenmuller [France]Source :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 1976.
Abstract
Abstract: The reaction of rare-earth nitrides with fluorides or the pyrolysis of these fluorides in gaseous ammonia atmosphere leads, in the case of lanthanum, cerium, and gadolinium, to nitride fluorides of general formula LnNxF3−3x. They crystallize with a fluorite-type structure which can be described in a consistent manner in terms of a Willis model. The magnetic properties of Gd3NF6 have been studied.
Url:
DOI: 10.1016/0022-4596(76)90122-5
Affiliations:
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Le document en format XML
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<front><div type="abstract" xml:lang="en">Abstract: The reaction of rare-earth nitrides with fluorides or the pyrolysis of these fluorides in gaseous ammonia atmosphere leads, in the case of lanthanum, cerium, and gadolinium, to nitride fluorides of general formula LnNxF3−3x. They crystallize with a fluorite-type structure which can be described in a consistent manner in terms of a Willis model. The magnetic properties of Gd3NF6 have been studied.</div>
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