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Les fluoronitrures de terres rares

Identifieur interne : 004C86 ( Main/Exploration ); précédent : 004C85; suivant : 004C87

Les fluoronitrures de terres rares

Auteurs : Michel Pezat [France] ; Bernard Tanguy [France] ; Marcus Vlasse [France] ; Josik Portier [France] ; Paul Hagenmuller [France]

Source :

RBID : ISTEX:F8A256C37ED7D0C1E14882CA94FA1CC202157985

Abstract

Abstract: The reaction of rare-earth nitrides with fluorides or the pyrolysis of these fluorides in gaseous ammonia atmosphere leads, in the case of lanthanum, cerium, and gadolinium, to nitride fluorides of general formula LnNxF3−3x. They crystallize with a fluorite-type structure which can be described in a consistent manner in terms of a Willis model. The magnetic properties of Gd3NF6 have been studied.

Url:
DOI: 10.1016/0022-4596(76)90122-5


Affiliations:


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